Effect of Hydrophilic Monomer Distribution on Self‐Assembly of a pH‐Responsive Copolymer: Spheres, Worms and Vesicles from a Single Copolymer Composition - Le Mans Université Accéder directement au contenu
Article Dans Une Revue Angewandte Chemie International Edition Année : 2020

Effect of Hydrophilic Monomer Distribution on Self‐Assembly of a pH‐Responsive Copolymer: Spheres, Worms and Vesicles from a Single Copolymer Composition

Sylvain Prevost

Résumé

Copolymers of acrylic acid (AA) and butyl acrylate (BA) with constant overall composition (1:1 AA:BA) and controlled composition profiles (gradient, asymmetric diblock and asymmetric triblock) show dynamic pH-responsive self-assembly behavior, with reversible changes in size and formation of sphere, worm and vesicle morphologies, in contrast to the frozen micelles formed by poly(AA-block-BA) block copolymers.

Domaines

Chimie
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Dates et versions

hal-03031355 , version 1 (16-11-2021)

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Junliang Zhang, Barbara Farias‐mancilla, Ihor Kulai, Stephanie Hoeppener, Barbara Lonetti, et al.. Effect of Hydrophilic Monomer Distribution on Self‐Assembly of a pH‐Responsive Copolymer: Spheres, Worms and Vesicles from a Single Copolymer Composition. Angewandte Chemie International Edition, 2020, ⟨10.1002/anie.202010501⟩. ⟨hal-03031355⟩
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