Poly(1,4-butadiene)-graft-poly(L-lactide) via the grafting-from strategy - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Polymer Bulletin Année : 2017

Poly(1,4-butadiene)-graft-poly(L-lactide) via the grafting-from strategy

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Résumé

Poly(1,4-butadiene)-graft-poly(L-lactide) copolymers were efficiently prepared via the grafting-from strategy using a combination of ring-opening metathesis polymerization (ROMP) of a hydroxyl-functionalized cyclobutene monomer and organocatalyzed ring-opening polymerization (ROP) of L-lactide. The copolymers were characterized by NMR, MALDI-TOF, SEC, TGA, and DSC demonstrating that well-defined polyester-grafted poly(1,4-butadiene) were obtained through the reported methodology.
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Dates et versions

hal-01905392 , version 1 (25-10-2018)

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Flavien Leroux, V. Montembault, Sandie Piogé, Sagrario Pascual, Laurent Fontaine. Poly(1,4-butadiene)-graft-poly(L-lactide) via the grafting-from strategy. Polymer Bulletin, 2017, 74 (11), pp.4415 - 4422. ⟨10.1007/s00289-017-1961-y⟩. ⟨hal-01905392⟩
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